Dry Cleaning Plant located in Boston, Massachusetts
Site Summary
Dry cleaning solvents were found in the soil under a parking lot adjacent to a large dry cleaning plant located in a mixed commercial and residential suburb of Boston, Massachusetts. The contamination was traced back to a storm water catch basin in the parking lot which contained sediment and sludge with high concentrations of the dry cleaning solvent perchloroethene (PCE). The sludge and catch basin were removed, but the contaminated ground water had migrated under the dry cleaning plant and adjacent residential properties. While most of the mass of ground water contamination remained under the parking lot, the low concentrations under residential properties were enough to raise concerns about potential vapor intrusion hazards. CL-Out bioremediation was implemented in the parking lot area to reduce the volume of contamination in the source area and mitigate future potential off-property risks.
Geology
The setting of the site is a complex glacial region of interbedded tills and channel deposits. The surface material at the site was mostly interbedded silt and sand lenses that formed a water bearing zone of varying permeability.
Hydrogeology
The affected aquifer was an unconfined silty sand zone approximately 25 feet thick. Monitoring wells were screened at two levels in the aquifer to assess the potential for DNAPL. Shallow wells were screened at the water table (10 to 20 feet deep). Deep monitoring wells were screened at the bottom of the perched aquifer approximately 25 to 35 feet deep.
Contamination
The size of ground water plume that resulted from leaching soil contaminants was estimated to be 13,000 square feet. The contamination was mainly PCE, trichloroethene (TCE) and cis 1,2-dichloroethene (DCE).
Remediation Design
CL-Out bioremediation was implemented in the ground water in the source area. Four existing monitoring wells were used for the injections. Surrounding monitoring wells were sampled to assess the progress of the remediation. The ground water was periodically inoculated for a period of 18 months. During each inoculation three units (165 gallons) of CL-Out were injected.
After 18 months of treatment, the contaminant concentrations in the source area were reduced by as much as 99%. The following charts show the contaminant reduction in the source area.
|
Contaminant Concentrations (µg/L) |
PCE |
TCE |
DCE |
Vinyl Chloride |
|
Shallow Source Well |
Pre-Treatment |
88,000 |
3,600 |
1,100 |
ND |
Post-Treatment |
750 |
110 |
320 |
150 |
Deep Source Well |
Pre-Treatment |
28,000 |
590 |
230 |
ND |
Post-Treatment |
32 |
12 |
44 |
1,100 |
Down gradient Shallow Well |
Pre-Treatment |
29,000 |
730 |
610 |
ND |
Post-Treatment |
3,400 |
580 |
930 |
ND |
Results
While the remediation objective of over all mass reduction was achieved in the source area, there is an indication that there was an accumulation in breakdown products. Although the pre-treatment presence of vinyl chloride may have been masked by high detection limits, the vinyl chloride concentration may have increased due to anaerobic degradation by native bacterial populations. The accumulation of vinyl chloride can be prevented by maintaining aerobic conditions in the aquifer during bioremediation.
The cost for CL-Out treatment was $18,000.
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